Mechanism of gas-phase aldose-ketose iso
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Ya-Jun Zheng; Andreas Staempfli; Julie A. Leary
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Article
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1993
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Elsevier Science
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English
β 564 KB
Fast-atom bombardment tandem mass spectrometry and the semiempirical molecular orbital method were used to investigate the mechanism of gas-phase aldose-ketose isomerization process in lithiated 1,3 linked disaccharide isomers. Both the 1,3 hydrogen shift and hydride transfer mechanisms were investi