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Gas Phase Reaction of Neutral Carbon Disulfide with Its Hydride Adduct Anions: Tandem Mass Spectrometry and Theoretical Studies

✍ Scribed by Gimbert, Y.; Arnaud, R.; Tabet, J.-C.; de Hoffmann, Ed.


Book ID
127188537
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
142 KB
Volume
102
Category
Article
ISSN
1089-5639

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## Abstract The complex potential energy surface of the gas‐phase reaction of HB(H)BH^βˆ’^ with CS~2~ to give three low‐lying products [B~2~H~3~S]^βˆ’^+CS, [BH~2~CS]^βˆ’^+HBS, and [BH~3~CS]+BS^βˆ’^, involving nine [B~2~H~3~CS~2~]^βˆ’^ isomers and 12 transition states, has been investigated at the CCSD(T)/6‐3