Stability, association, and dissociation
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Meot-Ner, M.; Field, F. H.
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Article
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1977
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American Chemical Society
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English
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Cluster ion stabilities were measured by pulsed, high-pressure mass spectrometry. Enthalpies for the reactions H,O+.( n -1)HzO + HzO + M -H,O+.nH20 + M were measured as -33.0, -21.0, and -16.0 kcal/mol for n = I , 2, and 3, respectively, in good agreement w i t h values obtained by Kebarle and co-wo