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First Characterization of the Ammine−Ammonium Complex [{NH 4 (NH 3 ) 4 } 2 (μ-NH 3 ) 2 ] 2+ in the Crystal Structure of [NH 4 (NH 3 ) 4 ][B(C 6 H 5 ) 4 ]·NH 3 and the [NH 4 (NH 3 ) 4 ] + Complex in [NH 4 (NH 3 ) 4 ][Ca(NH 3 ) 7 ]As 3 S 6 ·2NH 3 and [NH 4 (NH 3 ) 4 ][Ba(NH 3 ) 8 ]As 3 S 6 ·NH 3

✍ Scribed by Rossmeier, Thomas; Reil, Markus; Korber, Nikolaus


Book ID
120497211
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
202 KB
Volume
43
Category
Article
ISSN
0020-1669

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First Characterization of an Extended Am
✍ Thomas Rossmeier; Nikolaus Korber 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 12 KB 👁 1 views

## Structure D 2000 First Characterization of an Extended Ammonium-Ammonia Complex 1 ∞ [{NH4(NH3)4} + (µ-NH3)2] in the Crystal Structure of [NH4(NH3)4][Co(C2B9H11)2]•2NH3. -The title compound is prepared by reaction of Na[Co(C2B9H11)2] with a proton-charged ion exchange resin in liq. NH3 (Amberlys