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Gas-Phase Reactivity of Carboxylic Acid Functional Groups with Carbodiimides

✍ Scribed by Boone M. Prentice, Joshua D. Gilbert, John R. Stutzman, William P. Forrest, Scott A. McLuckey


Book ID
118303517
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
402 KB
Volume
24
Category
Article
ISSN
1044-0305

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πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Carboxylic Acids: S
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The molecular gas-phase elimination kinetics of the series CI(CH,).COOH (n = 1-4), show changes in mechanisms from polar five-centered intramolecular displacement of the CI leaving group by the acidic hydrogen of the COOH to neighboring group participation of the oxygen carbonyl of the COOH group. T