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Gas-phase reactions of chloro- and bromoanisoles with methyl- and dimethylamine via radical cations

✍ Scribed by Detlef Thölmann; Susanne Hamann; Hans-Friedrich Grützmacher

Book ID
103602568
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
961 KB
Volume
137
Category
Article
ISSN
0168-1176

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Unimolecular gas-phase reactions of the
Unimolecular gas-phase reactions of the methyl acetoacetate radical cation. Oxygen atom permutation via ion-molecule complexes
✍ Dorothée Berthomieu; Jeanine Tortajada; Jean-Pierre Morizur; Henri-Edouard Audie 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 588 KB

The reactions of metastable decomposing methyl acetoacetate (a mixture of keto and enol tautomers) are reported and discussed. The unimolecular fragmentations of the tautomers are different. The metastable decomposing radical cation of the keto form displays four specific ions: [ M -CO] +', IM -CHzO