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Gas-phase reactions between RO2 and NO, HO2 or CH3O2: correlations between rate constants and the SOMO energy of the peroxy (RO2) radical

✍ Scribed by Martin D. King; Carlos E. Canosa-Mas; Richard P. Wayne

Book ID
114377309
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
132 KB
Volume
35
Category
Article
ISSN
1352-2310

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πŸ“œ SIMILAR VOLUMES

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Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co

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Disproportionation/combination rate constant ratios, k , / k , , have been measured for the collision between CF3CH2CH2 and CF3 radicals to be 0.022 ? 0 002 and for CF3CH2CH2 and CF3CH2CH2 radicals to be 0.100 IT 0.002. Comparison to previous work from this laboratory for the reaction of CF3CH2CHCI