𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Gas-phase rate coefficients for the reaction of 3-hydroxy-2-butanone and 4-hydroxy-2-butanone with OH and Cl

✍ Scribed by Messaadia, L.; El Dib, G.; Lendar, M.; Cazaunau, M.; Roth, E.; Ferhati, A.; Mellouki, A.; Chakir, A.

Book ID
125438299
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
535 KB
Volume
77
Category
Article
ISSN
1352-2310

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

The Enol of Acetone during Photochemical
The Enol of Acetone during Photochemical Reactions of 3-Hydroxy-3-methyl-2-butanone and of Acetone
✍ Gary P. Laroff; H. Fischer πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 German βš– 555 KB

## Abstract The enol of acetone, formed by disproportionation reactions of 1‐hydroxy‐1‐methylethyl radicals, is detected by NMR, spectroscopy during photoreactions of 3‐hydroxy‐3‐methyl‐2‐butanone in acetonitrile and of acetone in 2‐propanol and slowly tautomerizes to acetone. The photolysis of 3‐h

Pyrolysis of Ξ²-hydroxyketones and Ξ±-keto
Pyrolysis of Ξ²-hydroxyketones and Ξ±-ketoesters: Gas-phase elimination kinetics of 3-hydroxy-3-methyl-2-butanone and methyl benzoylformate
✍ Nouria A. Al-Awadi; Osman M. E. El-Dusouqui πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 105 KB πŸ‘ 1 views

The rates of gas-phase elimination reactions of methyl benzoylformate (1) and 3hydroxy-3-methyl-2-butanone (2) were obtained at T Ο­ 600 K. The two substrates undergo unimolecular first-order elimination for which the Arrhenius equations are, respectively, log k Ο­ 13.2 Οͺ 53270/(4.574 Ο« 600) for (1) a