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Gas-phase ozonolysis of cis- and trans-dichloroethylene

✍ Scribed by Cary W. Blume; I. C. Hisatsune; Julian Heicklen

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
1013 KB
Volume
8
Category
Article
ISSN
0538-8066

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✦ Synopsis

Dichloroethylene (DCE), either czs or trans, was reacted with 0 3 at 23Β°C in both NZ and 0 2 buffered mixtures. Both reactant consumption and product formation were monitored by infrared spectroscopy and, in some cases, 0 3 consumption was monitored by ultraviolet absorption. For thoroughly dried mixtures, the initial products were only HCClO and Oz, but geometrical isomerization also occurred. The stoichiometry of the overall reaction always was

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