Gas-Phase Ozonolysis of Alkenes. Recent Advances in Mechanistic Investigations †
✍ Scribed by Horie, Osamu; Moortgat, Geert K.
- Book ID
- 126609127
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 123 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0001-4842
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## Abstract The ozonolysis of olefinic species is an important tropospheric process impacting on climate and human health. However, few studies have investigated these reactions as a function of temperature and even less information is available upon the effects of alkene heteroatomic substitution
Hexafluoro acetone CF 3 COCF 3 has been shown to react rapidly with the CH 2 OO, CH 3 CHOO, and (CH 3 ) 2 COO intermediates that are formed in the ozonolysis of C 2 H 4 , trans-2-C 4 H 8 , and 2,3-dimethyl-2-butene, respectively, and to form products tentatively assigned to the corresponding seconda