Is the hydroxyl radical formed in the gas-phase ozonolysis of alkenes?
✍ Scribed by Schäfer, C.; Horie, O.; Crowley, J. N.; Moortgat, G. K.
- Book ID
- 119694425
- Publisher
- American Geophysical Union
- Year
- 1997
- Tongue
- English
- Weight
- 455 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1944-8007
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Ozonolysis of C,H, was carried out at 295 K in 730 torr synthetic air in the concentration ranges of 10310 = I 9-8.2 ppm and [C2H41(, = 4 0-15.0 ppm, in the absence and presence of the added HCOOH [Ipprn), CH,COOH (1-10 pprn), and CH,OH (36-100 ppm]. In the absence of the added compounds, a nearly c
Receired 2-I Jul) 1979 B\_r using a combination of 3 microreactor A irh m.ttri\-ESR spectroscopy the gas phase ozonol~ sis of ethq Iene and cisbutene 0.1s imestig-ated. For residence times in the order of milliseconds the existence of radicals WZIS proten. The ESR signal nuy m;tinlv be attributed to