Gas phase kinetics of pyrolysis of 1-methyl-1-cyclopropene
β Scribed by Hopf, Henning ;Wachholz, Gerhard ;Walsh, Robin
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1985
- Tongue
- English
- Weight
- 520 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Gas-phase kinetics / Ring-opening of 3,3-dimethylcyclopropene / Vinylcarbene intermediates The gas-phase pyrolysis of 3.3-dimethylcyclopropene (1) in the temperature range of 185 -225Β°C gives 3-methyl-I-butyne (2) (91%) and isoprene (3) YO). The gas-phase pyrolysis of 3,3-dimethyl-I -trimethylsilylc
The gas phase pyrolysis of 1,1,1,2-tetrachloropropane was studied in a ,static system and seasoned vessel over the temperature range of 393.0-452.8"C and pressure range of 27.5-1 18.5 torr. The reaction is homogeneous, unimolecular, follows a first-order rate law, and is not affected by the presence
## Gas-phase pyrolysis reactions of 4(2Π ) (Scheme 1) have been carried out. The rates of gas-phase pyrolytic reactions of compounds 3, 4, 5, and 7 have been measured and found to correspond to unimolecular first-order reactions. Product analyses together with kinetic data were used to outline a
The elimination kinetics of the title compounds were carried out in a static system over the temperature range of 290-330Β°C and pressure range of 29.5-124 torr. The reactions, carried out in seasoned vessels with ally1 bromide, obey first-order rate law, are homogeneous and unimolecular. The tempera