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Gas-phase ion chemistry of NF3/SO2 mixtures: A mass spectrometric and theoretical investigation

✍ Scribed by Paola Antoniotti; Roberto Rabezzana; Francesca Turco; Stefano Borocci; Nicoletta Bronzolino; Felice Grandinetti


Book ID
108146561
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
401 KB
Volume
266
Category
Article
ISSN
1387-3806

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## Abstract The ion–molecule reactions occurring in GeH~4~/NF~3~, GeH~4~/SF~6~, and GeH~4~/SiF~4~ gaseous mixtures have been investigated by ion trap mass spectrometry and __ab initio__ calculations. While the NF~__x__~^+^ (__x__ = 1–3) react with GeH~4~ mainly by the exothermic charge transfer, th

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## Abstract The xenon–difluoronitrenium ion F~2~NXe^+^, a novel xenon–nitrogen species, was obtained in the gas phase by the nucleophilic displacement of HF from protonated NF~3~ by Xe. According to Møller–Plesset (MP2) and CCSD(T) theoretical calculations, the enthalpy and Gibbs energy changes (Δ