Gas-Phase Chemistry of Protonated Ethylamine: A Mass Spectrometric and Molecular Orbital Study
✍ Scribed by Bouchoux, Guy; Djazi, Feyçal; Nguyen, Minh Tho; Tortajada, Jeanine
- Book ID
- 121705605
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 299 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0022-3654
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## Abstract Proton‐transfer reactions that proceed within methanol cluster ions were studied using an electron impact time‐of‐flight mass spectrometer. When CH~3~OH seeded in helium is expanded and ionized by electron impact, the protonated species, (CH~3~OH)~__n__~H^+^, are the predominant cluster
Ab initio molecular orbital calculations at the MP2/6-31G\*//MP2/6-31G\* + ZPE level have been performed in order to explore the reaction between CH 3 OH 2 + and CH 3 OH. The detailed mechanism of proton transfer, CH 3 OH 2 + + CH 3 OH ® CH 3 OH + CH 3 OH 2 + , and of cationic nucleophilic substitut