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Gas-phase deprotonation of arylalkylamines. A collision-induced dissociation study

✍ Scribed by Ana M. Cardoso; Sílvia M. G. Alexandre; Cristina M. F. Barros; A. J. Ferrer Correia; Nico M. M. Nibbering

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
49 KB
Volume
13
Category
Article
ISSN
0951-4198

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✦ Synopsis

2 O as ionizing reagents, is discussed. The negative chemical ionization mass spectra show that, in the absence of a hydroxy group in the aromatic ring, deprotonation takes place at the benzylic position whereas the proton is lost from the OH group when present. The nitro compound forms only M ÀÁ ions. The CID spectra of the deprotonated molecules show that fragmentations are strongly dependent on the structural features of the molecules, namely the presence or absence of substituents in the aromatic ring or aliphatic chain.

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