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A close-coupling study of collision-induced dissociation in He + H2

✍ Scribed by K. Nobusada; K. Sakimoto; K. Onda

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
471 KB
Volume
233
Category
Article
ISSN
0009-2614

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✦ Synopsis

The previous quantum mechanical close-coupling study of the dissociative collisions in He + Hz (T-shape configuration) by the present authors [Chem. Phys. Letters 216 (1993) 6131 has been extended to a wide range of the total energy 4.8-7.5 eV. The dissociation process shows a clear vibrational enhancement. The dissociation probability has an undulation as a function of the total energy, and by using classical S-matrix theory it is shown that this feature is caused by interference of the contributions of multiple trajectories.

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