Gas-Phase Chemistry of Vanadium Oxide Cluster Cations. 2. Reactions with CH 2 F 2
β Scribed by Bell, R. C.; Zemski, K. A.; Castleman, A. W.
- Book ID
- 126836468
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 121 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
## Reaclrons of SlF2 rndlcnls have been sludled m a fast-flow syslem Rate conskm~s at 295 K of (47&03)~10-'~ cm' molecule-' s-' for the reactIon of SIFT + F2. and (5 1 +\_O 6)X1O-'3 cm' molecule-' s -' for SIF, + Cl, were obtamed No reacuon was observed with O2 and Hz SIF, wz detected by laser-Ind
As a result of an extensive delocalization of charge and a unique covalent structure, the cation has, in CH 3 OCH 2 ' e β ect, the character of an ambident electrophile. This cation can, on the one hand, be considered to be a classical electrophile. On the other hand, it may be considered to be a fac