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Gas-liquid chromatography and structure-retention time relationship of anhalonium alkaloids and related bases

✍ Scribed by Govind J. Kapadia; G. S. Rao


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
293 KB
Volume
54
Category
Article
ISSN
0022-3549

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✦ Synopsis


Gas

-Liquid Chromatography and Structure-Retention Time Relationship of Anhalonium Alkaloids and Related Bases EXPERIMENTAL Apparatus.-A Chromalab gas chromatograph equipped with hydrogen flame detector was used.

Column.-The column was made' of glass tube, 12 ft. in length and having an inner diameter of 4 mm. The liquid phase in the column was 1% methylsiloxane containing -5% phenyl substitution a and


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## Abstract The enantiomers of a series of fourteen __O__‐ethyl __O__‐(substituted) phenyl __N__‐isopropyl‐phosphoroamidothioates have been separated by high performance liquid chromatography (HPLC) on the Pirkle‐type chiral stationary phase. Seven molecular descriptors were calculated and four sig