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Gas Diffusion in Glassy Polymers by a Chain Relaxation Approach

✍ Scribed by Mi, Yongli; Lu, Xiaolin; Zhou, Jim


Book ID
126805937
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
85 KB
Volume
36
Category
Article
ISSN
0024-9297

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Dual-mode free volume model for diffusio
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The development of a new model for the diffusion of gas molecules in glassy polymers is presented which utilizes concepts from free volume theory and relies on a dual-mode interpretation of sorptive dilation in glassy polymers. Three assumptions are made in the development of the model. First, the f