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A Dual Mode, Local Equilibrium Relaxation Model for Small Molecule Diffusion in a Glassy Polymer

โœ Scribed by Guo, Juchen; Barbari, Timothy A.


Book ID
127351025
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
220 KB
Volume
41
Category
Article
ISSN
0024-9297

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Dual-mode free volume model for diffusio
โœ T. A. Barbari ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 202 KB ๐Ÿ‘ 2 views

The development of a new model for the diffusion of gas molecules in glassy polymers is presented which utilizes concepts from free volume theory and relies on a dual-mode interpretation of sorptive dilation in glassy polymers. Three assumptions are made in the development of the model. First, the f