## Abstract 2‐Hydroxy‐5‐methylbenzophenone (E) and (Z) oximes and 5,8‐diethyl‐7‐hydroxy‐6‐dodecanone (E) and (Z) oximes have been treated with N,O‐bis(trimethylsilyl)acetamide (BSA) to give di‐(trimethylsilyl) derivatives. The GLC data and the combined GC‐MS analysis of derivatized oximes are prese
Gas chromatographic studies of derivatives of celluline-like substances
✍ Scribed by Eva Tomori; H. Kalász; J. Nagy; J. Knoll
- Book ID
- 104146814
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 404 KB
- Volume
- 91
- Category
- Article
- ISSN
- 1873-3778
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✦ Synopsis
Different aspects of the gas chromatographic determination of the celluline-like substances exhibiting'specific cardiotonic activity are discussed. As this substance is isolated from frog skin and bladder, many impurities have to be considered. Determination of these samples, having a broad range of boiling points, was performed by means of programmed-temperature gas chromatography. Identification of unknown peaks was executed with the help of pure standard substances and retention indices.
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Gas chromatography has been used to measure low-coverage isosteric heats of adsorption of C1 to C6 alkanes on microporous carbons. The maximum enhancement in adsorption energy is approximately twice that of non-porous carbon and is given by samples which have a homogeneous micropore structure, consi