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Gas chromatographic separation of tricyclic compounds with bridgehead nitrogen atoms

✍ Scribed by P.J. Chivers; T.A. Crabb; R.O. Williams

Book ID
104146373
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
488 KB
Volume
45
Category
Article
ISSN
1873-3778

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✦ Synopsis

The diastereoisomeric mixtures of a series of unsubstituted and substituted perhyclrodipyrido[~,z-c; 2',1'-eJimidazoles (I), perhydropyrido[r,z-cJpyrrolo[z,r-e]imidazoles (II) and perhydrodipyrido[I,z-c; z'r'-fJpyrimidines (III), have been separated by preparative gas-liquid chromatography. Correlations have been made between the retention times and stereochemistry of the isomers in each mixture. *All the compounds discussed in this paper exist as racemates or in certain case optically inactive fo+m& **See Fig. z for the various configurations and prcfcrrcd conformations of these ,compounds. . .1.*1

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