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Gas chromatographic resolution of carbohydrate enantiomers. A new chiral phase for pentoses

✍ Scribed by Benecke, I. ;Schmidt, E. ;König, W. A.

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 203 KB
Volume: 4
Category: Article
ISSN: 0935-6304
DOI: 10.1002/jhrc.1240041103

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✦ Synopsis

Abstract

New chiral polymers have been prepared by conversion of cyano groups of polysiloxanes XE‐60 and OV‐225 into carboxylic groups and subsequent coupling to give the respective S‐valine‐R‐α‐phenyl‐ethyl amide. In contrast to the corresponding stationary phases with S‐α‐phenylethyl amide groups, which have been used for the resoultion of trifluoroacetylated hexose derivatives, the new phase show high enantioselectivity for pentose and 6‐deoxyhexose derivatives.

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