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Gas chromatographic determination of amines, aminoalcohols and acids after treatment with alkyl chloroformates

✍ Scribed by Petr Hušek; Zhi-Heng Huang; Charles C. Sweeley

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
466 KB
Volume
259
Category
Article
ISSN
0003-2670

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✦ Synopsis

Ammes such as tyramme, ttyptamme, spermme, and spemudme, ammoalcohols (catecholammes and related compounds), and their acuiic metabohtes were treated wth methyl or ethyl chloroformate m either sodmm bicarbonate solutlon (10 mm at 247'0 or m a medmm of aqueous acetomtrlle contammg methanol (or ethanol) and pyndme for Instantaneous derlvatlzatlon Gas chromatographx (GC) analysis revealed that ammoalcohols with a free alcohol group can be analyzed by GC with a fused-sdlca capdlary column and that the denvatrzatlon yields by both procedures were comparable Complete derwatrzatlon of the acxhc metabohtes, however, was possible only by the latter procedure Mass spectra of some of the derwatlzed compounds are Included kkywordr Gas chromatography, Akyl chloroformates, Ammes, Ammoalcohols

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