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Gas absorption with first-order chemical reaction in a spherical liquid film

✍ Scribed by G.A. Ratcliff; J.G. Holdcroft


Publisher
Elsevier Science
Year
1961
Tongue
English
Weight
838 KB
Volume
15
Category
Article
ISSN
0009-2509

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✦ Synopsis


The absorption rates of CO, and of 1, I-dimethoxyethane vapour into spherical liquid films in which they undergo fir&-order chemical reactiona have been measured. The difhion equation aeeuming an irreversible &t-order reaction haa been solved. The eolution has been used to calculate valuea of eZ +/D and the reaction velocity constant from the experimental absorption ratea. Good agreement with independent kinetic meaaurem enta of the velocity constant was obtained. The method may be used for the measurem ent of the kinetics of fast resctions. R&rmd-Mesure dea vitesae d'absorption de CO, et de vapeur de l,l-dlmethoxyethane dam des Alms liquidea apheriquee avec r&actions chiiulquea du ler ordre. L%quation de diffusion a & r&olue en euppoaant la reaction irreversible. La-solution a 6t.e utiliade pour calculer les valeum de c*dD e.t lee conatantea de vitease de la reaction B partir dea viteesea d'abaorption exp&imentales. Concordance avec la con&ante de vitesae obtenue par dea meaurea cinetiquee ind&endantea. La m6thode peut &re utili4e pour meaurer la cin4tique de r&actions rapidea. Zusamrpenfassuu-Die Absorptionsgeschwindigkeiten von CO, und 1, I-Dimethoxyaethrm-D&mpfen an kugelformigen PlilesigkeitaGhnen, in denen sie einer Reaktion I. Ordmmg unbzliegen, wurden gememen. Die Diffusionagleichung wurde unter der Axmahme einer irrevemiblen Reaktion I. Ordmmg gel&t. Diem L&mg wurde dazu benutzt, die Werte filr c* dD und die Reaktionageachwindigkeitskonatante au8 den experimentellen Absorptionegecchwindigkeiten zu berechnen. Es wurde eine gute ubereinstimmung mit davon unabhtingigen kinetiachen Meaumgen der Reaktionageachwlndigkeitekonatanten erzielt. Die Methode kann fur die Meesung der Rinetik achneller Reaktionen benutzt werden.


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