ฮณ-Silyl-stabilized tertiary ions? Solvol
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Leon J. Tilley; V. J. Shiner Jr
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Article
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1999
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John Wiley and Sons
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English
โ 143 KB
๐ 1 views
Rate constant, isotope-effect, and product studies of the solvolysis of 4-(trimethylsilyl)-2-chloro-2methylbutane, 11, and its carbon analog, 2-chloro-2,5,5-trimethylhexane, 10, in aqueous ethanol and aqueous 2,2,2trifluoroethanol (TFE) indicate very little participation of the g-silyl substituent.