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Gallium(III) iodide-promoted stereoselective aldol coupling of α,β-acetylenic ketones

✍ Scribed by J.S. Yadav; B.V.S. Reddy; Manoj K. Gupta; Sushil K. Pandey

Book ID
108212823
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
173 KB
Volume
264
Category
Article
ISSN
1381-1169

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## Abstract The efficient and highly stereoselective syntheses of a variety of (__Z__)‐configured, substituted __α__‐(hydroxymethyl)**‐**__β__‐iodo‐acrylates from prop‐2‐ynoate and various aldehydes was achieved. The synthetic protocol involves a simple one‐pot coupling reaction under mild conditio