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Gallium(III) and indium(III) alkoxides and aryloxides

✍ Scribed by Claire J. Carmalt; Simon J. King


Book ID
104010862
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
997 KB
Volume
250
Category
Article
ISSN
0010-8545

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✦ Synopsis


This article presents a systematic and extensive review of the syntheses, structures and reactivities of gallium(III) and indium(III) alkoxides and aryloxides. Mono-, bis-and tris(alkoxides) and (aryloxides) have been synthesised and structurally characterised for both gallium(III) and indium(III) and the applications of these compounds are also discussed.


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The polydentate tripodal Schiff base ligand H 3 L has been prepared by treating a methanolic solution of tris(aminoethyl)amine and 5-bromosalicylaldehyde. This ligand, and its complexes with group-13 metal ions (Ga III , In III , and Tl III ) have been characterized by elemental analysis, NMR spectr