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Tripodal Iminophenolate Ligand Complexes of Gallium(III), Indium(III), and Thallium(III)

✍ Scribed by Mélanie Figuet; Marie Thérèse Averbuch-Pouchot; Amaury du Moulinet d’Hardemare; Olivier Jarjayes


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
512 KB
Volume
2001
Category
Article
ISSN
1434-1948

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✦ Synopsis


The polydentate tripodal Schiff base ligand H 3 L has been prepared by treating a methanolic solution of tris(aminoethyl)amine and 5-bromosalicylaldehyde. This ligand, and its complexes with group-13 metal ions (Ga III , In III , and Tl III ) have been characterized by elemental analysis, NMR spectroscopy, FAB + -MS, and X-ray diffraction analysis. The ligand, not preorganized in the solid state, acts as a hexadentate N 3 O 3 ligand in all cases to form octahedral structures, the


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The adsorption mechanism of trivalent Ga and In onto g-Al 2 O 3 examined the sorption mechanisms of anions at the water/ was investigated using a triple-layer model simulation and presgoethite interface. The results of these works have indicated sure-jump technique. Bidentate Ga 3/ and In 3/ and mon