Further study of metal-metal bond lengths in homologous edge-sharing bioctahedral complexes
โ Scribed by Canich, Jo Ann M.; Cotton, F. Albert; Daniels, Lee M.; Lewis, Diane B.
- Book ID
- 126895939
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 677 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
w Ab initio configuration interaction calculations have been performed for the title compounds to study the nature of the metal-metal interaction. By analyzing the energy diagrams and the CI wave functions, it can be shown that the metal-metal interaction in such compounds has a dual nature, namely,
The dlfference between the metal-metal 6 and TT orbItal lonlzation energws for the complexes M~(OZCCF&, M2(02CCH3)4, M2(CaHsf.+\_ and Mz(hlHP)1, (where M = Cr or MO and H{MHP)= 6-methyl-2-hydrouypyrtdme) mcreases, wtthm each series. as the metal-metal bond length decreases. The vanahon m the metal-m