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Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes

✍ Scribed by Thorp, H. Holden


Book ID
127367609
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
586 KB
Volume
31
Category
Article
ISSN
0020-1669

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Correlation of metal-metal bond lengths
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The dlfference between the metal-metal 6 and TT orbItal lonlzation energws for the complexes M~(OZCCF&, M2(02CCH3)4, M2(CaHsf.+\_ and Mz(hlHP)1, (where M = Cr or MO and H{MHP)= 6-methyl-2-hydrouypyrtdme) mcreases, wtthm each series. as the metal-metal bond length decreases. The vanahon m the metal-m