Further studies on the transformations of unsaturated aldehydes by fermenting baker's yeast: a facile synthesis of l-olivomycose

A facile synthesis of optically pure L-a

A facile synthesis of optically pure L-armentomycin and its D-isomer.Highly enantioselective reduction of the CC double bond of methyl (E)- and (Z)-2,4,4-trichloro-2-butenoate by using baker's yeast

✍ Masanori Utaka; Satoshi Konishi; Toshiyasu Okubo; Sadao Tsuboi; Akira Takeda 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 192 KB

Optically pure L-armentomycin t(S)-2-amino-4,4-dichlorobutanoic acid] and its D-isomer [(R)-2-amino-4,4-dichlorobutanoic acid] were prepared by using methyl (E)-and (Z)-2,4,4-trichloro-2-butenoate as key intermediate, which were reduced with baker's yeast to (R)-and (S)-2,4,4-trichlorobutanoate in 8