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Further studies on carbon-carbon bond formation based on the radical reactions of acyl derivatives of N-hydroxy-2-thiopyridone

✍ Scribed by Derek H.R. Barton; Jadab C. Sarma

Book ID
104222158
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
199 KB
Volume
31
Category
Article
ISSN
0040-4039

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Radical nitrile transfer with methanesul
Radical nitrile transfer with methanesulfonyl cyanide or p-toluenesulfonyl cyanide to carbon radicals generated from the acyl derivatives of N-hydroxy-2-thiopyridone
✍ Derek H.R. Barton; Joseph Cs. Jaszberenyi; Emmanouil A. Theodorakis πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 237 KB

Reaction of methanesulfonyl cyanide or p-toluenesulfonyl cyanide with carbon radicals generated from the acyl derivatives of N-hydroxy-2-thiopyridone gives the corresponding nitriles in high yield. A mechanistic scheme is suggested. There are many synthetic applications of carbon radicals generated