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Further Studies on a Samarium Diiodide-Promoted Reductive Carbon—Nitrogen Bond Cleavage Reaction: Synthesis of (+)-Aphanorphine.

✍ Scribed by Miho Katoh; Hiroshi Inoue; Toshio Honda


Book ID
102008711
Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Application of Sama
✍ Toshio Honda; Chihiro Hisa 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 23 KB 👁 2 views

## Abstract The application of the samarium diiodide fragmentation reaction to 5,5‐disubstituted oxopyrrolidines (I) leads to a regioselective carbon—nitrogen bond cleavage affording the 4,4‐disubstituted cleavage products (II).