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ChemInform Abstract: Application of Samarium Diiodide-Promoted Reductive Carbon—Nitrogen Bond Cleavage Reaction to 3-Oxopyrrolidine Derivatives: Alternative Synthesis of a Coccinellid Alkaloid, (-)-Adalinine.

✍ Scribed by Toshio Honda; Chihiro Hisa

Publisher: John Wiley and Sons
Year: 2010
Weight: 23 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201035204

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✦ Synopsis

Abstract

The application of the samarium diiodide fragmentation reaction to 5,5‐disubstituted oxopyrrolidines (I) leads to a regioselective carbon—nitrogen bond cleavage affording the 4,4‐disubstituted cleavage products (II).

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