Furanodecalin synthesis using intramolecular Diels-Alder reactions of vinylfurans
β Scribed by John A Cooper; Philip Cornwall; Colin P Dell; David W Knight
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 258 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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The intramolecular tiiels-Alder reaction of several substituted cyclopentadienes to functionalized tricyclic products, suitable for transformation to polyquinane natural products, is described. We have embarked on what promises to be an extremely versatile strategy for the synthesis 'of natural prod
The first examples of intramolecular Diels-Alder reactions on indoles indicate that this reaction may be employed for the direct preparation of highly functionalized dihydroindoles. The hybridization of the atoms in the tether plays a crucial role.