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Functionalization of saturated hydrocarbons. 14. Further studies on the mechanism of Gif-type systems

✍ Scribed by Barton, Derek H. R.; Halley, Frank; Ozbalik, Nubar; Schmitt, Martine; Young, Esme; Balavoine, Gilbert

Book ID
111642515
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
783 KB
Volume
111
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

The selective functionalization of satur
The selective functionalization of saturated hydrocarbons. Part 36. Stereoselectivity studies of Gif-type reactions
✍ Derek H.R. Barton; Warinthorn Chavasiri πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 352 KB

The stereoselectivity of various Gif-type reactions was evaluated using trans-l,4-dimethylcyclohexane as a chemical probe. The results revealed that these reactions were moderately stereoselective. The outcome of the reactions was preferentially formed in the more stable equatorial configuration.

The functionalization of saturated hydro
The functionalization of saturated hydrocarbons. Part 23. Gif-type bromination and chlorination of saturated hydrocarbons: a non-radical reaction
✍ Derek H.R. Barton; Γ‰va Csuhai; DarΓ­o Doller πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 863 KB

The bromination of saturated hydrocarbons was studied in the GoAggln system using CBrCls and other polyhaloalkanes. This bromination reaction was compared to free radical processes by (i) evaluating the rates of reactions for a series of polyhaloalkanes, by (ii) measuring the selectivity of the diff