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Functionalization of Indene.

✍ Scribed by Ahmet Tutar; Osman Cakmak; Metin Balci

Publisher
John Wiley and Sons
Year
2006
Weight
30 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract Au/Ag‐Catalyzed cycloisomerization of a variety of o‐alkynylstyrene derivatives, e.g. (I) and (VII), proceeds with moderate to high enantioselectivity (up to 92% e.e.) in the presence of an axially chiral MeO‐biphep ligand to give alkenyl‐substituted indenes (II) and (VIII), resp., in h