ChemInform Abstract: Gold(I)-Catalyzed Enantioselective Synthesis of Functionalized Indenes.
✍ Scribed by Alberto Martinez; Patricia Garcia-Garcia; Manuel A. Fernandez-Rodriguez; Felix Rodriguez; Roberto Sanz
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 58 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
Au/Ag‐Catalyzed cycloisomerization of a variety of o‐alkynylstyrene derivatives, e.g. (I) and (VII), proceeds with moderate to high enantioselectivity (up to 92% e.e.) in the presence of an axially chiral MeO‐biphep ligand to give alkenyl‐substituted indenes (II) and (VIII), resp., in high yields.
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