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Functionalization of aromatic molecules using HOF.cntdot.CH3CN and CH3OF

✍ Scribed by Kol, Moshe; Rozen, Shlomo


Book ID
120489098
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
348 KB
Volume
58
Category
Article
ISSN
0022-3263

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The reaction of the HOF\*CHQCN complex, made directly by passing fluorine through aqueous acetonitrile, with some phenanthrene and pyrene derivatives results in fast epoxidation.

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## Abstract In the presence of HOFΒ·CH~3~CN, a wide range of thienopyrroles can be transformed efficiently into the corresponding S,S‐dioxides at 25 Β°C.