ChemInform Abstract: Synthesis of Oxidized Thienopyrroles Using HOF·CH3CN.
✍ Scribed by Neta Shefer; Shlomo Rozen
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 37 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
In the presence of HOF·CH~3~CN, a wide range of thienopyrroles can be transformed efficiently into the corresponding S,S‐dioxides at 25 °C.
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Tertiary Amine Oxidation Using HOF•CH 3 CN: A Novel Synthesis of N-Oxides. -HOF•MeCN reacts with various tertiary amines such as pyridine derivatives, phenanthroline, aliphatic and alicyclic amines to afford the corresponding N-oxides under very mild conditions (0-25 • C) in a few minutes and in go
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