Functionalisation of the α position of acrylate systems by the addition of carbonyl compounds: Highly pressure-dependent reactions.
✍ Scribed by Jonathan S. Hill; Neil S. Isaacs
- Book ID
- 104219198
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 191 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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As we haVe previously pointed out], the position of the Transition State along the reaction coordinate is a matter of controversy among workers in the field of nucleophilic addition reactions to carbonyl compounds. Some authors claim that the transition state is always "Reactant-like" whatever may b
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We describe a new method for the preparation of dihydroquinazoline-2-thione and 4H-3,1-benzothiazine-2-thione derivatives by intramolecular heteroconjugate addition of carbodiimides or isothiocyanates bearing one o-substituted a,b-unsaturated carbonyl fragment promoted by the CS 2 /TBAF system.