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Functional metallomacrocycles and their polymers, Part 34. Catalytic oxygenation of cyclohexene by water-soluble polymer containing manganese phthalocyanine complex

✍ Scribed by Mutsumi Kimura; Tadayoshi Nishigaki; Toshiki Koyama; Kenji Hanabusa; Hirofusa Shirai


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
547 KB
Volume
29
Category
Article
ISSN
1381-5148

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Functional metallomacrocycles and their
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## Abstract The decomposition reaction of hydrogen peroxide by a water‐soluble polymer containing phthalocyanine‐Mn (1c, 1d) was studied in aqueous solution. The catalase‐like activity was varied by the kind of added nitrogen base and its concentration. The catalase‐like activity is also dependent

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## Abstract The catalytic autoxidation of 2‐mercaptoethanol was studied by using new water‐soluble polymers containing a cobalt(II) phthalocyaninate complex as a catalyst. The phthalocyanine vinyl‐monomer, 2‐acryloylamino‐9,16,23‐tri‐__tert__‐butylphthalocyanine (APc(t‐Bu)~3~), was synthesized and