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Functional metallomacrocycles and their polymers. Part 31. Autoxidation of thiol by temperature-sensitive polymer catalyst containing cobalt(II) phthalocyanine complex

✍ Scribed by Mutsumi Kimura; Tadayoshi Nishigaki; Toshiki Koyama; Kenji Hanabusa; Hirofusa Shirai

Publisher
Elsevier Science
Year
1994
Weight
384 KB
Volume
23
Category
Article
ISSN
0923-1137

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Functional metallomacrocycles and their
Functional metallomacrocycles and their polymers, 26. Synthesis of 2-acryloylamino-9,16,23-tri-tert-butylphthalocyanine and autoxidation of thiol with water-soluble polymers containing cobalt(II) phthalocyaninate complex
✍ Mutsumi Kimura; Tomohiro Dakeno; Etsuko Adachi; Toshiki Koyama; Kenji Hanabusa; 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 497 KB

## Abstract The catalytic autoxidation of 2‐mercaptoethanol was studied by using new water‐soluble polymers containing a cobalt(II) phthalocyaninate complex as a catalyst. The phthalocyanine vinyl‐monomer, 2‐acryloylamino‐9,16,23‐tri‐__tert__‐butylphthalocyanine (APc(t‐Bu)~3~), was synthesized and