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Fully regioselective catalytic carbonylation of acrylic derivatives: synthesis of methylmalonic acid by iron pentacarbonyl-catalyzed hydrocarboxylation of acrylic acid

โœ Scribed by Brunet, Jean Jacques; Passelaigue, Elisabeth


Book ID
126397618
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
390 KB
Volume
9
Category
Article
ISSN
0276-7333

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The regioselectivity of alkoxycarbonylation of 1-arylethanols catalysed by Pdracid systems is very sensitive to the nature of the counter anion of the acid: chloride anion favours branched products while tetrafluoroborate and sulfonates anions favour linear products, the latter ones enhancing also p