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FTIR spectroscopic observation of peroxyalkyl nitrates formed via ROO + NO2 → ROONO2

✍ Scribed by H. Niki; P.D. Maker; C.M. Savage; L.P. Breitenbach

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 287 KB
Volume: 55
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)87020-1

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✦ Synopsis

Kinetic and spectroscopic evidente has been obtained for the formation of psroxyaIky1 nitrates via RCO + NO* -ROONO2 (R = C,H,,+, , n = 1-6) using Cl-atom sensitized oxidation of alkane-NO2 mixtures and a long path Fourier transform IR spectroscopic detection method.

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