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FTIR spectroscopic observation of haloalkyl peroxynitrates formed via ROO + NO2 → ROONO2 (R  CCI3, CFCI2 and CF2CI)

✍ Scribed by H. Niki; P.D. Maker; C.M. Savage; L.P. Breitenbach

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 429 KB
Volume: 61
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)85095-2

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✦ Synopsis

FORMED VIA ROO f NO2 + ROONO? (R = CC13, CFC12 AND CF+I) H. NIKI, P-D_ MAKER, CJi_ SAVAGE and i_P_ BREITENBACH Grrl Resear& Smff. Dmmhom. _~lichjymz -iSI fl. i.51 Receiwd 6 Sotember I578 Kicetic and sprrtroszopic rrld,-ncr has been obtzincd for the forrmtiun of haIoalhy1 pero) nitrates via the gas phase reactions ROO a X&_(+>l) -KOOS02<+W <R = CC13. CI'CI= and C&Cl)_ The possibility is raised tht these ructiocs may panicipatc in stra:osphtric chrmistry_ I_ introduction Recentty, kinetic and spectroscopic evidence 113s been obtained in this laboratory for the formation of 3kyl peroxynitmtes, ROOSO, (R = C,liIl,l+t, !I = O-61, via gas phrisc reactions of ROO \ ith X0? 113 _

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✍ H. Niki; P.D. Maker; C.M. Savage; L.P. Breitenbach 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 287 KB

Kinetic and spectroscopic evidente has been obtained for the formation of psroxyaIky1 nitrates via RCO + NO\* -ROONO2 (R = C,H,,+, , n = 1-6) using Cl-atom sensitized oxidation of alkane-NO2 mixtures and a long path Fourier transform IR spectroscopic detection method.