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FTIR gas-phase kinetic study on the reactions of OH radicals and Cl atoms with unsaturated esters: Methyl-3,3-dimethyl acrylate, (E)-ethyl tiglate and methyl-3-butenoate

✍ Scribed by Colomer, Juan P.; Blanco, María B.; Peñéñory, Alicia B.; Barnes, Ian; Wiesen, Peter; Teruel, Mariano A.

Book ID
121765929
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
656 KB
Volume
79
Category
Article
ISSN
1352-2310

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✍ Gaia Fantechi; Niels R. Jensen; Jens Hjorth; Jozef Peeters 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 2 views

Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 Ϯ 2 K 740 Ϯ 5 torr pressure are: Ϫ11 3 Ϫ1 Ϫ1 Ϫ18 3 k ϭ (3.9 Ϯ 1.