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FTIR and FT Raman Spectra of B6O

✍ Scribed by H. Werheit; U. Kuhlmann


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
216 KB
Volume
133
Category
Article
ISSN
0022-4596

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✦ Synopsis


The IR active phonon spectrum of B 6 O is typical for the -rhombohedral boron structure group. The number of phonons corresponds exactly to that predicted by group theory. The phonon bands in the spectrum are weakly damped, indicating that the structure is largely undistorted. Contrary to the IR spectrum the FT Raman spectrum exhibits no narrow lines but considerably broadened bands. This leads to the conclusion that the strong optical excitation by the Nd : YAG laser with about 2 W irradiation power causes a considerable distortion of the structure by fluctuations in consequence of the interaction between optically excited electrons and intraicosahedral phonons.


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