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FT-IR, FT-Raman and SERS spectra of anilinium sulfate

✍ Scribed by P. L. Anto; R. J. Anto; H. T. Varghese; C. Y. Panicker; D. Philip; A. G. Brolo

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
157 KB
Volume
40
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

The FT‐IR and FT‐Raman spectra of anilinium sulfate were recorded and analyzed. The surface‐enhanced Raman scattering (SERS) was recorded from a silver electrode. The vibrational wavenumbers of the compound have been computed using the Hartree‐Fock/6‐31G* basis and compared with the experimental values. The molecule is adsorbed on the silver surface with the benzene ring in a tilted orientation. The presence of amino and sulfate group vibrations in the SERS spectrum reveal the interaction between amino and sulfate groups with the silver surface. The direction of the charge transfer contribution to SERS has been discussed from the frontier orbital theory. Copyright Β© 2009 John Wiley & Sons, Ltd.

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